Clusters for alkyne-azide click reactions.

نویسندگان

  • Philipp Heinz
  • Michael Puchberger
  • Maria Bendova
  • Stefan O Baumann
  • Ulrich Schubert
چکیده

The clusters Ti(6)O(4)(OPr)(8)(OOC(CH(2))(2)C[triple bond]CH)(8) and [Zr(6)O(4)(OH)(4)(OOC(CH(2))(3)C[triple bond]CH)(12)](2) with acetylenic carboxylate ligands were prepared and structurally characterized in solution and in the crystalline state. Model reactions showed that they are suitable candidates for the formation of cluster-based inorganic-organic hybrid materials by alkyne-azide click reactions.

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عنوان ژورنال:
  • Dalton transactions

دوره 39 33  شماره 

صفحات  -

تاریخ انتشار 2010